Author | S.T. Huxtable, D.G. Cahill, S. Shenogin & P. Keblinski |
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Title | Relaxation of vibrational energy in fullerene suspensions |
Year | 2005 |
Journal | Chemical Physics Letters |
Volume | 407 |
Pages | 129-134 |
Editor | Elsevier B.V. |
Abstract | Picosecond transient absorption is used to measure the thermal decay time of a mixture of higher-order fullerenes suspended in chloroform, toluene, and carbon disulfide. The relaxation time is 40 ps, which translates into a small effective interface conductance, G 14 MW m_2 K_1. Molecular dynamics simulations of a fullerene molecule suspended in octane agree with experiment (G 10 MW m_2 K_1) and support the conclusion that the 40 ps decay time results from the relaxation of vibrational energy and not the relaxation of electronic excitations. |
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